铜基正弦波微通道内流动沸腾传热特性试验研究

基于超快激光技术加工铜基正弦波弯曲型微通道，以去离子水为流动工质，在不同质量流量和热通量条件下，对弯曲型微通道内流动沸腾特性进行试验研究。基于温度/压力数据和流动可视化结果，发现通道传热系数随出口干度增大，呈迅速增大后减小并趋于稳定趋势，正弦波微通道相较直微通道具有更好的换热性能，传热系数最大提高127.7%，压降仅增加14.4%。波状通道结构能明显抑制流动沸腾中不稳定现象发生。通过可视化试验发现，随热通量增大，流型经历泡状流-弹状流-环状流的转变，换热主导机制由核态沸腾逐渐过渡到薄液膜蒸发。     

The formation of fibrous structure of polyamide 6 induced by the three-step forming process and its prominent reinforcement in nitrile rubber

Nitrile rubber (NBR) blends with excellent performance have always been a hot research topic in petroleum field. Due to the excellent performance and compatibility of polyamide 6 (PA6), it provides an opportunity for the preparation of high-performance NBR/PA6 blends. In this article, NBR/PA6 blends were prepared by the three-step molding process. Experimentally, it was found that PA6 has a prominent reinforcement effect in NBR matrix. The variation of this mechanical property was investigated from different aspects of the crystal structure, crystallinities, phase morphology, and so on. It can be cleared that the formation of fibrous structure of PA6 phase is the main factor for reinforcement of the polymer blends. Meanwhile, the formation mechanism of the special phase structure induced by the three-step process is deeply expounded and its structural evolution schematic is established. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47472.     

广西某黄铁矿化蚀变砂泥岩型金矿选矿试验研究

广西某金矿为黄铁矿化蚀变砂泥岩型金矿,可回收金主要为黄铁矿、脉石包裹金。金矿物绝大部分为次显微金、胶体金及晶格金,呈均匀分布,极难单体解离,因此金矿物较难富集。试验研究结果表明,采用浮选—尼尔森联合工艺获得金粗精矿金品位为5.82g/t,金回收率为88.85%,较单一浮选工艺粗选金回收率提高5.19%;闭路试验结果表明,采用浮选—尼尔森联合工艺可获得金品位为12.53g/t、金回收率为88.48%的金精矿,较好地实现了该金矿的综合回收。     

改进卷积输入的端到端普通话语音识别

主流神经网络训练的交叉熵准则是对声学数据的每个帧进行分类优化，而连续语音识别是以序列级转录准确性为性能度量。针对这个不同，构建基于序列级转录的端到端语音识别系统。针对低资源语料条件下系统性能不佳的问题，其中模型使用卷积神经网络对输入特征进行处理，选取最佳的网络结构，在时域和频域进行二维卷积，从而改善输入空间中因不同环境和说话人产生的小扰动影响。同时神经网络使用批量归一化技术来减少泛化误差，加速训练。基于大型的语言模型，优化解码过程中的超参数，提高模型建模效果。实验结果表明系统性能提升约24%，优于主流语音识别系统。     

Modeling of an industrial scale hydrodynamic cavitation multiphase reactor for Prileschajew epoxidation

The hydrodynamic cavitation multiphase reactor (HCMR) is emerging as a promising alternative for the intensification of liquid–liquid heterogeneous reactions, but research on HCMR modeling is lacking. In this article, an HCMR model was developed using Prileschajew epoxidation as the model system. First, based on experimental measurements of oil/water two-phase flow downstream of hydrodynamic cavitation devices, semiempirical correlations were proposed to describe the droplet size and droplet size distribution (DSD) as functions of flow conditions and geometry parameters. Then, with boundary conditions calculated by the DSD correlation, a droplet dynamics simulation in a reaction tank was performed by computational fluid dynamics coupled with population balance model to obtain the two-phase interfacial area. Finally, the acquired reactor model was substituted into an overall kinetic model, to simulate the epoxidation reaction in HCMR. Model predictions were verified by experimental results measured on an industrial scale HCMR.     

Light-responsive color switching of self-doped TiO2-x/WO3·0.33H2O hetero-nanoparticles for highly efficient rewritable paper

Smart materials that reversibly change color upon light illumination are widely explored for diverse appealing applications.However,light-responsive color switching materials are mainly limited to organic molecules.The synthesis of inorganic counterparts has remained a significant challenge because of their slow light response and poor reversibility.Here,we report a seeded growth strategy for the synthesis of TiO_2-x/WO₃·0.33H₂Ohetero-nanoparticles(HNPs)with networked wire-like structure of?10 nm in diameters that enable the highly reversible light-responsive color switching properties.For the TiO_2-x/WO₃·0.33H₂OHNPs,T P species self-doped in TiO_2-xnanoparticles(NPs)act as efficient sacrificial electron donors(SEDs)and Ti-O-W linkages formed between TiO2-x and WO30.33H2O NPs ensure the nanoscale interfacial contact,endowing the HNPs enhanced photoreductive activity and efficient interfacial charge transfer upon ultraviolet(UV)illumination to achieve highly efficient color switching.The TiO_2-x/WO₃·0.33H₂OHNPs exhibits rapid light response(<15 s)and long reversible color switching cycles(>180 times).We further demonstrate the applications of TiO_2-x/WO₃·0.33H₂O HNPs in ink-free,light-printable rewritable paper that can be written on freehand or printed on through a photomask using UV light.This work opens an avenue for designing inorganic light-responsive color switching nanomaterials and their smart applications.